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In the single-phase region (superheated steam)
\(\ \ \ \ DF = 2\)
Must specify two properties to define the thermodynamic state
e.g. What is the specific volume of steam at \(5\ \mathrm{bar}\) and \(300\ ^\circ\mathrm{C}\)?
e.g. What is the temperature of steam with a specific volume of \(0.50000\) \(\dfrac{\textrm{m}^3}{\textrm{kg}}\) at \(5\) bar?
\(\dfrac{T - 250}{0.50000 - 0.47443}\ =\ \dfrac{300 - 250}{0.52260-0.47443} \hspace{5pt} \Rightarrow T = 276.54 ^{\circ} \mathrm{C}\)
In the two-phase region (saturated steam and water)
\(\ \ \ \ DF = 1\)
Have two phases (water and steam) in equilibrium.
e.g. What is the temperature, and what are the specific enthalpies of saturated water and saturated steam at \(5.0\) bar?
In the two-phase region (saturated steam and water)
We know the properties of the two phases.
What is the property of the overall mixture?
Define the quality.
\(\ \ \ \ x \equiv \dfrac{m_\mathrm{steam}}{m_\mathrm{steam} + m_\mathrm{water}} = \dfrac{m_\mathrm{steam}}{m_\mathrm{total}}\)
What is the pressure and specific internal energy of a mixture of steam and water at \(88\ ^\circ\mathrm{C}\) and a quality of \(80\%\)?
\(P=0.65017\ \mathrm{bar}\)
\(\hat{U}_{\text{mix}} = x\hat{U}_{v} + (1-x)\hat{U}_{l} = 0.8 \mathbf{\cdot} 2491.5 + 0.2 \mathbf{\cdot} 368.49 = 2066.9\ \mathrm{kJ/kg}\)
\(\hat{U}_{\text{mix}} = x\hat{U}_{v}\ +\ (1-x)\hat{U_{l}} = x(\hat{U}_{v} - \hat{U}_{l}) + \hat{U}_{l} = x\Delta \hat{U}_{lv} + \hat{U}_{l}\)
\(\hat{U}_{\text{mix}} = x\Delta \hat{U}_{lv} + \hat{U}_{l} = 0.8\mathbf{\cdot} 2123.0 + 368.49 = 2066.9\ \mathrm{kJ/kg}\)
What is the quality of a mixture of steam and water at \(0.65017\) bar, and a specific enthalpy of \(2000\ \mathrm{kJ/kg}\)?
\(\hat{H}_{\text{mix}} = x\hat{H}_{v}\ +\ (1-x)\hat{H_{l}} = x(\hat{H}_{v} - \hat{H}_{l}) + \hat{H}_{l} = x\Delta \hat{H}_{lv} + \hat{H}_{l}\)
\(\\\)
\(x = \dfrac{\hat{H}_{\mathrm{mix}} - \hat{H}_{l}}{\hat{H}_{v} - \hat{H}_{l}} = \dfrac{2000 - 368.55}{2656.3 - 368.55} = 0.7131 = 71.31\)%
\(\\\)
\(x = \dfrac{\hat{H}_{\text{mix}} - \hat{H}_{l}}{\Delta\hat{H}_{lv}} = \dfrac{2000 - 368.55}{2287.7} = 0.7131 = 71.31\)%
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